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IJSTR >> Volume 10 - Issue 8, August 2021 Edition



International Journal of Scientific & Technology Research  
International Journal of Scientific & Technology Research

Website: http://www.ijstr.org

ISSN 2277-8616



Tailoring The Vibrational Infrared And Raman Spectra Of Samarium Oxide Doped Magnesium Tellurite Glass Containing Silver Nanoparticles

[Full Text]

 

AUTHOR(S)

Nurulhuda Mohammad Yusoff, Md Rahim Sahar, Siti Maisarah Aziz, Salmiah Jamal Mat Rosid, Siti Noor Syuhada

 

KEYWORDS

Glass, Samarium, Fourier Transform Infrared Spectroscopy, Raman Spectroscopy

 

ABSTRACT

The material under investigation was tellurite glass based composition of (89.6-x)TeO2-10MgO-(x)Sm2O3-0.4AgCl with 0.2 ≤ x ≤ 1.2 mol% glass system. The glass samples have been synthesised by a conventional melt quenching technique. The amorphous nature has been verified by X-ray diffraction pattern. The effect of samarium doping on the structural properties of glass system was performed by FTIR and Raman spectroscopy. Analysis of FTIR and Raman spectroscopy indicated the presence of three main bands attributed to the structural units, [TeO4] tbp, [TeO3+1] polyhedral, and [TeO3] tp. The substitution of samarium ion, Sm3+ at different concentration in the glass structure led to the appearance of overlapping band and shifting of wavenumber. This demonstrated that, Sm3+ significantly transformed [TeO4] tbp to [TeO3] tp through [TeO3+1] polyhedral. The structural change was discussed in terms of formation of bridging oxygen (BO) and non-bridging oxygen (NBO) with respect to glass composition. The formation of NBO was responsible to decrease the connectivity of the tellurite glass former network.

 

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